B. C. Hess, I. G. Okhrimenko,
R. C. Davis, B. C. Stevens, Q. A. Schulzke, K. C. Wright, C. D. Bass, and S. L. Summers (et al.)
CdSe nanocrystals in solution and films can enter a metastable state in which the highly luminescent nanocrystals become dark. This change, which we attribute to a surface transformation, can be caused by heating or by changing the environment of the nanocrystals at room temperature. The metastable transformation is reversed upon illumination of above-band-gap light, at which point the nanocrystals are again highly luminescent.